高比例清洁能源下水风光消纳能力分析方法研究

建立了基于出库流量和耗水率的水电站水库模型，并考虑了来水衰减因子和来水时延因子的梯级水电站来水关联关系，以提升水电站时序模拟精度。为最大程度消纳水风光等清洁电力，通过考虑水风光出力特性、负荷特性、机组调峰能力以及电网网络传输等约束，建立了清洁能源时序生产模拟模型。建立的模型为混合整数模型，通过分支定界法进行求解。以实际电网参数构建的仿真系统为例，对水风光消纳过程进行定量化分析。计算结果验证了清洁能源时序生产模型以及水库建模的合理性和有效性，对我国清洁能源实际运行和消纳具有积极意义。     

Scalable Production of Wearable Solid-State Li-Ion Capacitors from N-Doped Hierarchical Carbon

Smart and wearable electronics have aroused substantial demand for flexible portable power sources, but it remains a large challenge to realize scalable production of wearable batteries/supercapacitors with high electrochemical performance and remarkable flexibility simultaneously. Here, a scalable approach is developed to prepare wearable solid-state lithium-ion capacitors (LICs) with superior performance enabled by synergetic engineering from materials to device architecture. Nitrogen-doped hierarchical carbon (HC) composed of 1D carbon nanofibers welded with 2D carbon nanosheets is synthesized via a unique self-propagating high-temperature synthesis (SHS) technique, which exhibits superior electrochemical performance. Subsequently, inspired by origami, here, wave-shaped LIC punch-cells based on the above materials are designed by employing a compatible and scalable post-imprint technology. Finite elemental analysis (FEA) confirms that the bending stress of the punch-cell can be offset effectively, benefiting from the wave architecture. The wearable solid-state LIC punch-cell exhibits large energy density, long cyclic stability, and superior flexibility. This study demonstrates great promise for scalable fabrication of wearable energy-storage systems.     

Optimization of C/TiCx duplex diffusion barrier coatings for SiCf/Ti composites based on interfacial structure evolution exploration

Introducing a carbon single coating is a popular method used to protect SiC_f/Ti composites from severe interface reactions. However, carbon coatings lose their protective effect on SiC fibres at high temperature, even after a short period time. As such, given the strong demand for high temperature applications in aeronautics and astronautics a more coating which is more effective at high temperatures is desirable. In order to improve the high temperature interfacial stability of SiC_f/Ti composites, a C/TiC_x duplex coating system with different C contents in TiC_x was introduced to explore the protection of fibres at 1200?°C for 1?h. The results show that the C/quasi-stoichiometric TiC coating system protects the SiC fibres most effectively. Based on insights from the evolution of the interface structure, TiC_x has been identified as an interfacial reaction product from the C single coating, exhibiting a gradient in C content and grain size, which is different from a deposited TiC layer with a well-distributed composition and structure. The different coating structure gives rise to different ability to resist C diffusion at high temperatures, in which poor resistance ability appears in TiC_x interfacial reaction layer coming from C single coating due to short-circuit diffusion in C-rich fine-grained TiC layer and fast intracrystalline diffusion trigged by amounts of vacancies in sub-stoichiometric coarse-grained TiC layer. Therefore, C/quasi-stoichiometric TiC duplex coatings with a thick, coarse-grained quasi-stoichiometric TiC layer could effectively inhibit C diffusion by comparison to C single coatings, and is more effective than C/rich-carbon TiC duplex coatings due to the existence of short-circuit diffusion in the latter. As such, C/quasi-stoichiometric TiC duplex coatings appear to be an optimal diffusion barrier for SiC_f/Ti composites at high temperature.     

Knowledge convergence and organization innovation: the moderating role of relational embeddedness

Knowledge convergence is an important means of innovation. The study aims to explore how knowledge convergence influences innovation performance at an organizational level. Furthermore, we address the moderating role of network relational embeddedness on the innovation deriving from knowledge convergence. Our empirical analyses adopting negative binomial regression models employ patent counts and patent citations from the nanotechnology field. The findings reveal that the scientific intensity in the convergence between scientific knowledge and technological knowledge has an inverted U-shaped influence on innovation performance and that this association is flattened in organizations with high network relational diversity. Also, we find that the technological scope in convergence of technological knowledge self has an inverted U-shaped influence on innovation performance and that this association is steepened in organizations with high network relational strength. Our findings add understandings of knowledge convergence on organization innovation and also have important practical and political implications.

     

间隙配合变轨距轮对与轨道间瞬态滚滑接触模拟研究

变轨距技术是实现不同轨距铁路联运的重要手段，我国相关研究仍在起步阶段。基于显式有限元法，建立包含渐开线花键副的三维变轨距轮对-轨道耦合瞬态分析模型，于时域内模拟速度高至400 km/h下的瞬态轮轨滚滑和花键间动态接触行为及其相互影响。模型充分考虑轮轨和花键副三维几何、系统高频结构振动等，引入时变牵引/制动转矩，采用集成库仑摩擦定律的"面-面"接触算法求解轮轨接触和花键接触。假设圆柱直齿渐开线花键，齿数取32，齿侧间隙恒0.1 mm，无激励下模拟结果表明，花键副的存在使得轮轨力波动范围大于传统轮对，例如，400 km/h下法向轮轨力波动幅值增加静载的3.7%。时速400 km/h和牵引系数0.05下，内外花键的径向和角向偏置使得花键左、右两侧各存在1个位置相对固定的承载区，各涉及5~6个键齿，承载面分别为II和I键齿工作面。瞬态法、切向接触应力极值发生在靠近一系悬挂侧的齿根或齿顶部，典型值分别为102 MPa和4.6 MPa，任一键齿的应力极值因不断有键齿进出承载区而波动上升和下降。牵引系数0.3时，左侧承载区消失，右侧承载区扩至18个键齿，相同时刻下的法、切向接触应力极值因承载齿数和总接触面积增加变为89 MPa和5.2 MPa。为变轨距机构中花键的强度和动力学分析及相关设计提供精确模拟手段。     

An effective approach for reliability-based robust design optimization of uncertain powertrain mounting systems involving imprecise information

The uncertain parameters of automotive powertrain mounting systems (PMSs) may involve imprecise information (e.g., incomplete, different and conflicting information) in engineering practice. An effective approach is proposed for the reliability-based robust design optimization (RBRDO) of uncertain PMSs involving imprecise information. In the proposed approach, the imprecise information of uncertain parameters is firstly addressed and combined based on evidence theory, and the uncertain parameters are treated as evidence variables. Then, an uncertainty analysis method named evidence perturbation-central difference method (EPCDM) is derived to fast estimate the mean intervals, standard deviation intervals, and the belief and plausibility measures related to system inherent characteristics. A reference method named evidence-Monte Carlo method (EMCM) is developed to verify the effectiveness of EPCDM. Next, to conduct robustness design, the weighted sum of the lower bounds of means and the upper bounds of standard deviations of system inherent characteristics are taken to construct optimization objective; while to perform reliability design, the belief measures related to system inherent characteristics are used to create reliability constraints. Afterwards, a nested RBRDO model is established to explore the optimum design of the PMS, which considers both reliability and robustness simultaneously. The nested PBRDO can be effectively simplified based on EPCDM. The effectiveness of the proposed approach is finally demonstrated by the application example.

     

A General Strategy for Antimony-Based Alloy Nanocomposite Embedded in Swiss-Cheese-Like Nitrogen-Doped Porous Carbon for Energy Storage

Due to its suitable working voltage and high theoretical storage capacity, antimony is considered a promising negative electrode material for lithium-ion batteries (LIBs) and has attracted widespread attention. The volume effect during cycling, however, will cause the antimony anode to undergo a severe structural collapse and a rapid decrease in capacity. Here, a general in situ self-template-assisted strategy is proposed for the rational design and preparation of a series of M Sb (M = Ni, Co, or Fe) nanocomposites with M N C coordination, which are firmly anchored on Swiss-cheese-like nitrogen-doped porous carbon as anodes for LIBs. The large interface pore network structure, the introduction of heteroatoms, and the formation of strong metal N C bonds effectively enhance their electronic conductivity and structural integrity, and provide abundant interfacial lithium storage. The experimental results have proved the high rate performance and excellent cycling stability of antimony-based composite materials. Electrochemical kinetics studies have demonstrated that the increase in capacity during cycling is mainly controlled by the diffusion mechanism rather than the pseudocapacitance contribution. This facile strategy can provide a new pathway for low-cost and high-yield synthesis of Sb-based composites with high performance, and is expected to be applied in other energy-related fields such as sodium-/potassium-ion batteries or electrocatalysis.     

Nanocellulose-based reusable liquid metal printed electronics fabricated by evaporation-induced transfer printing

Reusable electronics have received widespread attention and are urgently needed. Here, nanocellulosebased liquid metal(NC-LM) printed circuit has been fabricated by the evaporation-induced transfer printing technology. In this way, the liquid metal pattern is embedded into the nanocellulose membrane, which is beneficial for the stability of the circuit during use. Besides, the NC-LM circuit is ultrathin with just tens of microns. In particular, the finished product is environmentally friendly because it can be completely dissolved by water, and both the liquid metal ink and the nanocellulose membrane can be easily recollected and reused, thereby reducing waste and pollution to the environment. Several examples of flexible circuits have been designed to evaluate their performance. The mechanism of evaporation-induced transfer printing technology involves the deposition, aggregation, and coverage tightly of the nanosized cellulose fibrils as the water evaporated. This study provides an economical and environmentally friendly way for the fabrication of renewable flexible electronics.     

Effect of high hydrogen enrichment on the outer-shear-layer flame of confined lean premixed CH4/H2/air swirl flames

In this study, we investigated the H₂-induced transition of confined swirl flames from the “V” to “M” shape. H₂-enriched lean premixed CH₄/H₂/air flames with H₂ fractions up to 80% were conducted. The flame structure was obtained with Planar Laser-Induced Fluorescence (PLIF) of the OH radical. Flow fields were measured with Particle Image Velocimetry (PIV). It was observed that the flame tip in the outer shear layer gradually propagated upstream and finally anchored to the injector with the hydrogen fractions increase, yielding the transition from the “V” to “M” flame. We examined the flame structures and the flame flow dynamics during the transition. The shape transition was directly related to the evolution of the corner flame along the outer shear layer. With H₂ addition, the outer recirculation zone first appeared downstream where the corner flame started to propagate upstream; then, the recirculation zone expanded upward to form a stable “M” flame gradually. The flow straining was observed to influence the stabilization of the outer shear layer flame significantly. This study can be useful for the understanding of recirculation-stabilized swirling flames with strong confinement. The flame structure and the flow characteristics of flames with a high H₂ content are also valuable for model validation.